Search results for "Laws of thermodynamics"
showing 5 items of 5 documents
Boundary controlled irreversible port-Hamiltonian systems
2021
Abstract Boundary controlled irreversible port-Hamiltonian systems (BC-IPHS) defined on a 1-dimensional spatial domain are defined by extending the formulation of reversible BC-PHS to irreversible thermodynamic systems controlled at the boundaries of their spatial domain. The structure of BC-IPHS has clear physical interpretation, characterizing the coupling between energy storing and energy dissipating elements. By extending the definition of boundary port variables of BC-PHS to deal with the irreversible energy dissipation, a set of boundary port variables are defined such that BC-IPHS are passive with respect to a given set of conjugated inputs and outputs. As for finite dimensional IPHS…
SCALING THEORY AND THE CLASSIFICATION OF PHASE TRANSITIONS
1992
The recent classification theory for phase transitions (R. Hilfer, Physica Scripta 44, 321 (1991)) and its relation with the foundations of statistical physics is reviewed. First it is outlined how Ehrenfests classification scheme can be generalized into a general thermodynamic classification theory for phase transitions. The classification theory implies scaling and multiscaling thereby eliminating the need to postulate the scaling hypothesis as a fourth law of thermodynamics. The new classification has also led to the discovery and distinction of nonequilibrium transitions within equilibrium statistical physics. Nonequilibrium phase transitions are distinguished from equilibrium transiti…
Variation of extent of reaction in closed chemical equilibrium when changing the temperature at constant volume
2011
In this paper it is presented a thermodynamic analysis that aims to find the mathematical expression of the variation of extent of reaction with the infinitesimal variation in the temperature at constant volume of a chemical equilibrium mixture. The goal of this paper is to establish an alternative approach to avoid both the Le Chatelier's principle and the problems that emerge when trying to apply its qualitative statements. This attempt is based on the laws of thermodynamics.
Entropy flux in non-equilibrium thermodynamics
2004
Abstract An important problem in thermodynamics is the link between the entropy flux and the heat flux, for phenomena far from equilibrium. As an illustration we consider here the case of a rigid heat conductor subject to heating. The expression of the entropy flux is determined by the expressions of the evolution equations of the basic variables. It is shown that the coefficient relating entropy and heat fluxes differs far from equilibrium from the inverse of the non-equilibrium temperature θ . The particular case in which these two quantities are identical is examined in detail. A simple but intuitive physical illustration of the results is proposed. A comparison with information theory i…
Thermodynamics: Classical Framework
2016
This chapter starts with a summary of the thermodynamic potentials and the relationships between them which are obtained from Legendre transformation. This is followed by an excursion to some important global properties of materials such as specific heat, expansion coefficients and others. The thermodynamic relations provide the basis for a discussion of continuous changes of state which are illustrated by the Joule-Thomson effect and the Van der Waals gas. These are models which are more realistic than the ideal gas. The discussion of Carnot cycles leads to and illustrates the second and third laws of thermodynamics. The chapter closes with a discussion of entropy as a concave function of …